A series of InxAlyZnz (x≤0.15, y≤0.02 z ≥0.83) anodes that can form porous structure during battery cycling have been developed to achieve enhanced stability for zinc-based batteries. These anodes can be achieved through electrodeposition or other methods. These anodes during cycling result in a porous In2O3 surface that allows for zinc to be deposited into and onto the pores. The materials have result in lower cell polarization and higher cycle life without dendrite formation.